Photoelectric effect: Light of frequency ν > threshold frequency (ν₀) ejects electrons. Einstein's equation: KE_max = hν - hν₀ = hν - φ (φ = work function). Stopping potential V₀: eV₀ = hν - φ.
Key observations: (1) No electrons below threshold frequency regardless of intensity. (2) KE_max depends on ν, NOT intensity. (3) Number of electrons depends on intensity. (4) Emission is instantaneous. These observations CANNOT be explained by wave theory — established photon nature of light.
de Broglie wavelength: λ = h/mv = h/p. For electron accelerated through V: λ = h/√(2meV) = 1.227/√V nm. For photon: λ = hc/E = c/ν.
Heisenberg's uncertainty principle: Δx · Δp ≥ h/4π. Cannot simultaneously know exact position and momentum.
Postulates: Electrons move in fixed circular orbits (stationary states) without radiating. Energy absorbed/emitted = E = hν when electron jumps between orbits.
Allowed orbits: mvr = nh/2π (angular momentum quantised in multiples of h/2π = ℏ). n = 1, 2, 3... (quantum number).
Energy of nth orbit (H atom): Eₙ = -13.6/n² eV. E₁ = -13.6 eV (ground state), E₂ = -3.4 eV, E₃ = -1.51 eV. Ionisation energy = 13.6 eV.
Radius: rₙ = n²a₀ where a₀ = 0.529 Å (Bohr radius). r₁ = 0.529 Å, r₂ = 2.116 Å.
Spectral series: Lyman (UV, n→1), Balmer (visible, n→2), Paschen (IR, n→3), Brackett (IR, n→4), Pfund (IR, n→5).
α decay: ₂₃₈U → ₂₃₄Th + ₄He. A decreases by 4, Z decreases by 2. Heaviest nuclei decay by α.
β⁻ decay: Neutron → proton + electron + antineutrino. Z increases by 1, A unchanged. Neutron-rich nuclei.
β⁺ decay: Proton → neutron + positron + neutrino. Z decreases by 1, A unchanged.
γ decay: No change in A or Z — just energy emission from excited nucleus. Always accompanies α or β decay.
Radioactive decay law: N = N₀e^(-λt). Activity A = dN/dt = λN = λN₀e^(-λt). t½ = 0.693/λ = ln2/λ. Mean lifetime τ = 1/λ = 1.44 t½.
Mass defect: Δm = Zm_p + (A-Z)m_n - M_nucleus. Mass is converted to binding energy: BE = Δm × c².
Binding energy per nucleon: BE/A. Peaks at Fe-56 (~8.8 MeV/nucleon) → most stable nucleus. Light nuclei: fusion releases energy (BE/A increases). Heavy nuclei: fission releases energy (BE/A increases).
Nuclear reactions: Fission: ₂₃₅U + n → ₁₄₁Ba + ₉²Kr + 3n + energy. Fusion: ²H + ³H → ⁴He + n + 17.6 MeV. Fusion releases more energy per unit mass but requires extremely high temperature (sun operates by p-p chain fusion).
eV₀ = hν - φ (stopping potential)
φ = hν₀ = hc/λ₀
h = 6.626 × 10⁻³⁴ J·s
1 eV = 1.6 × 10⁻¹⁹ J
n=1: -13.6 eV (ground)
n=2: -3.4 eV
n=3: -1.51 eV
n=∞: 0 (ionised)
Ionisation energy: 13.6 eV
Balmer: n→2 (visible)
Paschen: n→3 (near IR)
Brackett: n→4 (IR)
Pfund: n→5 (far IR)
t½ = 0.693/λ
Activity A = λN
Mean life τ = 1/λ = 1.44t½
α: A-4, Z-2
β⁻: A same, Z+1
γ: A and Z unchanged
Bohr model / energy levels: 1–2 Q/year
Radioactive decay: 1 Q/year
Nuclear fission/fusion: 1 Q/year
Expected: Bohr energy level transition identification
Watch: de Broglie wavelength of particles
